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Yes, affiance is in the scrabble dictionary

...and is worth 18 points by itself.

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affiance

verb

1. To solemnly promise (oneself or another) in marriage .

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verb-transitive

1. To bind in a pledge of marriage; betroth.

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Here are some other words you could make with the letters affiance, you can also
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Top Words by points

Points

Word Game

affiance

16

Scrabble

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2 Letters

Scrabble® Points

if

5

ef

5

en

2

fa

5

fe

5

aa

2

in

2

na

2

ne

2

an

2

ai

2

ae

2

3 Letters

Scrabble® Points

iff

9

ice

5

fan

6

fin

6

fie

6

fen

6

nae

3

eff

9

ani

3

ane

3

can

5

caf

8

ace

5

aff

9

ain

3

ana

3

4 Letters

Scrabble® Points

fife

10

fine

7

cane

6

acai

6

naff

10

naif

7

neif

7

nice

6

niff

10

face

9

cine

6

cain

6

caff

12

cafe

9

acne

6

fief

10

fain

7

fane

7

fice

9

5 Letters

Scrabble® Points

aecia

7

finca

10

faena

8

facia

10

6 Letters

Scrabble® Points

fiance

11

fanfic

14

faciae

11

affine

12

7 Letters

Scrabble® Points

caffein

15

8 Letters

Scrabble® Points

affiance

16

Found 57 words in 0.32784 seconds