Scrabble Dictionary

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Yes, apostle is playable

...and is worth 11 points.

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TWL06 (NASPA List 2006)

"Apostle" Definition

noun

A leader of the first Christian mission to a country or region.
A missionary of the early Christian Church.
A passionate adherent; a strong supporter.
One of a group made up especially of the 12 disciples chosen by Jesus to preach the gospel.
One of the 12 members of the administrative council in the Mormon Church.