Scrabble Dictionary

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Yes, armed is playable

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Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Armed" Definition

adjective

Equipped, especially with a weapon.
Source: Wiktionary
Having an arm or arms.
Source: Wiktionary
Pertaining to the horns, teeth, or tusks of beasts or pertaining to the beaks and talons of birds when these parts are coloured in a different tincture from the beast or bird itself.
Source: Wiktionary
Prepared for use; loaded.
Source: Wiktionary
Furnished with weapons .

verb

Simple past tense and past participle of arm.
Source: Wiktionary