Scrabble Dictionary

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Yes, arrow is playable

...and is worth 8 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Arrow" Definition

noun

A missile having a straight thin shaft with a pointed head at one end and often flight-stabilizing vanes at the other, meant to be shot from a bow.
Something, such as a directional symbol, that is similar to an arrow in form or function.
A missile shot from a bow and usually having a slender shaft, a pointed head, and feathers at the butt.
Something shaped like an arrow.
A mark (as on a map or signboard) to indicate direction.

verb-intransitive

To move like an arrow.

verb

To move fast and straight like an arrow in flight .