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Yes, caliche is playable

...and is worth 16 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Caliche" Definition

noun

A crude sodium nitrate occurring naturally in Chile, Peru, and the southwest United States, used as fertilizer.
See hardpan.
See sodium nitrate.
The nitrate-bearing gravel or rock of the sodium nitrate deposits of Chile and Peru.
A crust of calcium carbonate that forms on the stony soil of arid regions.

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