Scrabble Dictionary

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Yes, ionosphere is playable

...and is worth 16 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Ionosphere" Definition

noun

The part of the earth's atmosphere in which ionization of atmospheric gases affects the propagation of radio waves, which extends from about 30 miles (50 kilometers) to the exosphere, and which is contiguous with the upper portion of the mesosphere and the thermosphere.
A comparable region of charged particles surrounding another celestial body (as Venus).

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