Scrabble Dictionary

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Yes, matron is playable

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"Matron" Definition

noun

A married woman or a widow, especially a mother of dignity, mature age, and established social position.
A woman who acts as a supervisor or monitor in a public institution, such as a school, hospital, or prison.
A married woman usually marked by dignified maturity or social distinction.
A woman who supervises women or children (as in a school or police station).
The chief officer in a women's organization.