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Yes, mediate is playable

...and is worth 11 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Mediate" Definition

adjective

Acting through, involving, or dependent on an intervening agency.
Being in a middle position.
Occupying a middle position.
Acting through an intervening agency.
Exhibiting indirect causation, connection, or relation.

verb-transitive

To bring about (a settlement, for example) by working with all the conflicting parties.
To effect or convey as an intermediate agent or mechanism.
To resolve or settle (differences) by working with all the conflicting parties: mediate a labor-management dispute.

verb-intransitive

To have a relation to two differing persons or things.
To intervene between two or more disputants in order to bring about an agreement, a settlement, or a compromise.
To settle or reconcile differences.

verb

To bring accord out of by action as an intermediary.
To effect by action as an intermediary.
To act as intermediary agent in bringing, effecting, or communicating.
To transmit as intermediate mechanism or agency.
To interpose between parties in order to reconcile them.

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