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Yes, methane is playable

...and is worth 13 points.

Found in the following dictionaries

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OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Methane" Definition

noun

An odorless, colorless, flammable gas, CH4, the major constituent of natural gas, that is used as a fuel and is an important source of hydrogen and a wide variety of organic compounds.
A colorless odorless flammable gaseous hydrocarbon CH that is a product of decomposition of organic matter and of the carbonization of coal, is used as a fuel and as a starting material in chemical synthesis, and is the simplest of the alkanes.

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