Scrabble Dictionary

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Yes, methenamine is playable

...and is worth 21 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Methenamine" Definition

noun

An organic compound, (CH2)6N4, used as a urinary tract antiseptic and in rubber vulcanizing. Also called hexamethylenetetramine.
Hexamethylenetetramine especially when used in the form of an organic salt to treat urinary tract infections.

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