Scrabble Dictionary

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Yes, molar is playable

...and is worth 9 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Molar" Definition

noun

A tooth with a broad crown used to grind food, located behind the premolars.
A tooth with a rounded or flattened surface adapted for grinding.
One of the cheek teeth in mammals behind the incisors and canines .

adjective

Capable of grinding.
Chemistry Containing one mole of a substance.
Chemistry Relating to or designating a solution that contains one mole of solute per liter of solution.
Of or relating to the molars.
Physics Of or relating to a body of matter as a whole, perceived apart from molecular or atomic properties.