Scrabble Dictionary

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Yes, motive is playable

...and is worth 13 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Motive" Definition

noun

A motif in art, literature, or music.
An emotion, desire, physiological need, or similar impulse that acts as an incitement to action.
Something (as a need or desire) that causes a person to act.
A recurrent phrase or figure that is developed through the course of a musical composition.

adjective

Causing or able to cause motion: motive power.
Impelling to action: motive pleas.
Of or constituting an incitement to action.
Moving or tending to move to action.
Of or relating to or the causing of motion .

verb-transitive

To motivate.