Scrabble Dictionary

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Yes, perfluorocarbon is playable

...and is worth 30 points.

Found in the following dictionaries

SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)

"Perfluorocarbon" Definition

noun

Any compound formally derived from a hydrocarbon by replacing each hydrogen atom with one of fluorine.
Source: Wiktionary
Any of various hydrocarbon derivatives in which all hydrogen atoms have been replaced with fluorine and that include blood substitutes used in emulsified form.
Any of a series of binary compounds of carbon and fluorine, analogous to hydrocarbons.

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