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Yes, pioneer is playable

...and is worth 11 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Pioneer" Definition

noun

A soldier who performs construction and demolition work in the field to facilitate troop movements.
Ecology An animal or plant species that establishes itself in a previously barren environment.
One who opens up new areas of thought, research, or development: a pioneer in aviation.
One who ventures into unknown or unclaimed territory to settle.
A member of a military unit usually of construction engineers.

adjective

Leading the way; trailblazing: a pioneer treatment for cancer.
Of, relating to, or characteristic of early settlers: the pioneer spirit.
Relating to or being a pioneer.
Of, relating to, or characteristic of early settlers or their time.

verb-intransitive

To act as a pioneer: pioneered in development of the laser.

verb-transitive

To initiate or participate in the development of: surgeons who pioneered organ transplants.
To open up (an area) or prepare (a way): rockets that pioneered outer space.
To settle (a region).

verb

To act as a pioneer .
To open or prepare for others to follow.
To originate or take part in the development of.

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