Scrabble Dictionary

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Yes, pique is playable

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TWL06 (NASPA List 2006)

"Pique" Definition

noun

A state of vexation caused by a perceived slight or indignity; a feeling of wounded pride.
A feeling of wounded .
A durable ribbed clothing fabric of cotton, rayon, or silk.
Decoration of a or ivory object with fragments of gold or silver.

verb-transitive

To cause to feel resentment or indignation.
To pride (oneself): He piqued himself on his stylish attire.
To provoke; arouse: The portrait piqued her curiosity.

verb

To anger or resentment in .
To excite or arouse especially by a provocation, challenge, or rebuff .