Scrabble Dictionary

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Yes, plain is playable

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Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Plain" Definition

noun

A broad level expanse, as a part of the sea floor or a lunar mare.
An extensive, level, usually treeless area of land.
Something free of ornamentation or extraneous matter.
An extensive area of level or rolling treeless country.
A broad unbroken expanse.

adjective

Archaic Having no visible elevation or depression; flat; level.
Common in rank or station; average; ordinary: a plain man.
Free from obstructions; open; clear: in plain view.
Lacking beauty or distinction: a plain face.
Marked by little or no ornamentation or decoration.

adverb

Informal Clearly; simply: plain stubborn.
In a plain manner without obscurity or ambiguity .