Is sister a word in the Scrabble Dictionary

Yes, sister is playable

...and is worth 6 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Sister" Definition

noun

A close woman friend or companion.
A fellow African-American woman or girl.
A fellow woman.
A female having the same parents as another or one parent in common with another.
A girl or woman who shares a common ancestry, allegiance, character, or purpose with another or others, specifically:.

adjective

Genetics Of or being one of an identical pair: sister chromatids.
Related by or as if by sisterhood; closely related: sister ships; sister cities.