Scrabble Dictionary

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Yes, solitary is playable

...and is worth 11 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Solitary" Definition

noun

A person who lives alone; a recluse.
Solitary confinement.
One who lives or seeks to live a solitary life.
Solitary confinement in prison.

adjective

Existing, living, or going without others; alone: a solitary traveler. See Synonyms at alone.
Happening, done, or made alone: a solitary evening; solitary pursuits such as reading and sewing.
Having no companions; lonesome or lonely.
Remote from civilization; secluded: a solitary retreat.
Single and set apart from others: a solitary instance of cowardice.