Scrabble Dictionary

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Yes, vocation is playable

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TWL06 (NASPA List 2006)

"Vocation" Definition

noun

A regular occupation, especially one for which a person is particularly suited or qualified.
An inclination, as if in response to a summons, to undertake a certain kind of work, especially a religious career; a calling.
A summons or strong inclination to a particular state or course of action.
A divine call to the religious life.
An entry into the priesthood or a religious order.