Scrabble Dictionary

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Yes, initiate is playable

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Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Initiate" Definition

noun

One who has been introduced to or has attained knowledge in a particular field.
One who is being or has been initiated.
A person who is undergoing or has undergone an .
A person who is instructed or adept in some special field.

adjective

Initiated or admitted, as to membership or a position of authority.
Instructed in esoteric knowledge.
Introduced to something new.
or properly admitted (as to membership or an office).
Instructed in some secret knowledge.

verb-transitive

To admit into membership, as with ceremonies or ritual.
To introduce to a new field, interest, skill, or activity.
To set going by taking the first step; begin: initiated trade with developing nations. See Synonyms at begin.

verb

To cause or facilitate the beginning of set going .
To induct into membership by or as if by special rites.
To instruct in the rudiments or principles of something .